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Giant magnetoresistance (GMR) is a quantum mechanical magnetoresistance effect observed in thin film structures composed of alternating ferromagnetic and nonmagnetic layers.
The effect manifests itself as a significant decrease in electrical resistance in the presence of a magnetic field. In the absence of an external magnetic field, the direction of magnetization of adjacent ferromagnetic layers is antiparallel due to a weak anti-ferromagnetic coupling between layers. The result is high-resistance magnetic scattering.
When an external magnetic field is applied, the magnetization of the adjacent ferromagnetic layers is parallel. The result is lower magnetic scattering, and lower resistance. [1]
The effect is exploited commercially by manufacturers of hard disk drives. The 2007 Nobel Prize in physics was awarded to Albert Fert and Peter Grünberg for the discovery of GMR.
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GMR was discovered in 1988 in Fe/Cr/Fe trilayers by a research team led by Peter Grünberg of the Jülich Research Centre (DE), who owns the patent. It was also simultaneously but independently discovered in Fe/Cr multilayers by the group of Albert Fert of the University of Paris-Sud (FR). The Fert group first saw the large effect in multilayers that led to its naming, and first correctly explained the underlying physics. The discovery of GMR is considered the birth of spintronics. Grünberg and Fert have received a number of prestigious prizes and awards for their discovery and contributions to the field of spintronics including the 2007 Nobel Prize in Physics.
In multilayer GMR two or more ferromagnetic layers are separated by a very thin (about 1 nm) non-ferromagnetic spacer (e.g. Fe/Cr/Fe). At certain thicknesses the RKKY coupling between adjacent ferromagnetic layers becomes antiferromagnetic, making it energetically preferable for the magnetizations of adjacent layers to align in anti-parallel. The electrical resistance of the device is normally higher in the anti-parallel case and the difference can reach more than 10% at room temperature. The interlayer spacing in these devices typically corresponds to the second antiferromagnetic peak in the AFM-FM oscillation in the RKKY coupling.
The GMR effect was first observed in the multilayer configuration, with much early research into GMR focusing on multilayer stacks of 10 or more layers.
In spin valve GMR two ferromagnetic layers are separated by a thin (~3 nm) non-ferromagnetic spacer, but without RKKY coupling. If the coercive fields of the two ferromagnetic electrodes are different it is possible to switch them independently. Therefore, parallel and anti-parallel alignment can be achieved, and normally the resistance is again higher in the anti-parallel case. This device is sometimes also called a spin valve.
Research to improve spin valves is intensely focused on increasing the MR ratio by practical methods such as increasing the interfacial resistance, or by inserting half metallic layers into the spin valve stack. These work by increasing the distances over which an electron will retain its spin (the spin relaxation length), and by enhancing the polarization effect on electrons by the ferromagnetic layers.
Spacer materials include Cu (copper), and ferromagnetic layers use NiFe (permalloy), which are both widely studied and meet industrial standards.
Spin valve GMR is the configuration most useful industrially and is the configuration used in hard drives.
Granular GMR is an effect that occurs in solid precipitates of a magnetic material in a non-magnetic matrix. To date, granular GMR has only been observed in matrices of copper containing cobalt granules. The reason for this is that copper and cobalt are immiscible, and so it is possible to create the solid precipitate by rapidly cooling a molten mixture of copper and cobalt. Granule sizes vary depending on the cooling rate and amount of subsequent annealing. Granular GMR materials have not been able to produce the high GMR ratios found in the multilayer counterparts.
GMR has been used extensively in the read heads in modern hard drives and magnetic sensors. Another application of the GMR effect is in magnetoresistive random access memory (MRAM), a type of non-volatile semiconductor memory. GMR has triggered the rise of a new field of electronics called [[spintronics]it.
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